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UID:submissions.pasc-conference.org_PASC24_sess113_msa137@linklings.com
SUMMARY:Atomistic Understanding of the Mechanical Behaviors of Polyamide I
 onene Self-Healing Elastomers
DESCRIPTION:Minisymposium\n\nEdward Buckser (The University of Vermont), J
 ason Bara (University of Alabama), and Jihong Ma (The University of Vermon
 t)\n\nIntrinsic self-healing (SH) polymers can repeatedly heal themselves 
 from mechanical damage by reorganizing their polymer matrices without addi
 ng healing reagents. Therefore, they have drawn significant attention to d
 eveloping sustainable SH soft materials. Recent studies have shown that io
 n-containing polymers can better harness SH features due to the additional
  strength of ionic interactions between chains. \nIn this work, we are mai
 nly interested in supramolecular dynamic chemistry, i.e., non-covalent bon
 ding dynamics, as they can repeatedly heal local damage. Although each non
 -covalent bond is weaker than its covalent counterparts, together, they ca
 n form strong polymer network systems and thus achieve high mechanical str
 ength. Particularly, we are interested in the roles of hydrogen bonding an
 d ionic interaction since they are both dynamic and subject to change upon
  external stimuli, such as heat or UV light. We will discuss how they affe
 ct the structural conformation and thermomechanical properties, as well as
  their competition with ionic interactions.\nThis work was supported by th
 e U.S. Department of Energy (DE-SC0023473) and the U.S. National Science F
 oundation (NSF Grant No. 2132055).\n\nDomain: Chemistry and Materials, Phy
 sics, Computational Methods and Applied Mathematics\n\nSession Chairs: Jan
  Michael Carrillo (Oak Ridge National Laboratory) and Jihong Ma (The Unive
 rsity of Vermont)
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